
Water entering the plant is called raw water. Upon entry, potassium permanganate is injected to convert
soluble ferrous iron to insoluble ferric iron so it can be filtered out. Another benefit to potassium
permanganate injection is the oxidation of hydrogen sulfide (which gives the rotten egg odor). This
oxidation process is vital to the plant operation in that it filters out iron and sulfur bacteria which would
otherwise deposit on the membrane surface and cause fouling. It also enables the City to "BLEND"
filtered water back with the reverse osmosis (R/O) product water to naturally stabilize the water. This
process will be discussed further during the stabilization process.
The water then enters the greensand pressure filters utilizing the water pressure provided by the supply
wells. The filters are constructed as horizontal cylinders with layers of filtering material. The top layer is
anthracite. It filters out the precipitated insoluble iron produced by the injection of the potassium
permanganate. Manganese greensand is the middle layer. This layer absorbs any residual potassium
permanganate left over in the water. It also filters out and converts any iron still left in the water at this
point. The final layers are multi-sized gravel to support the upper layers and provides filtering for any
particles which may have passed through the upper layers. All of the water entering the plant passes
through this iron removal process.
Sulfuric acid is added to lower the pH of the water to prevent calcium carbonate scaling on the R/O
membranes. Antiscalant (polyacrylic acid) is added to prevent calcium sulfate and barium sulfate scaling
on the membrane. Any scaling on the membrane surface would prevent the passage of the water through
the membrane. As scaling occurs, the pressure it takes to force the water through the membrane
increases, which in turn increases the power requirement.
After the injection of chemicals to prevent scaling on the membranes, the water passes through a series of
5 micron polypropylene cartridge filters. These remove any silt, turbidity, or debris larger than 5 micron
which could cause irreparable damage to the membrane surface. Bacteria or other organic matter can also
be filtered out during this process. The micron filters cannot be cleaned and/or reused. They are changed
out as the pressure loss across them dictates or the water quality from them deteriorates to a point that
possible damage to the R/O membranes could occur. This step is the last and most important in the
pre-treatment process the membranes. The water is then termed pre-treated feedwater. All treatment
done to this point is to protect the RO membranes from any scaling or fouling from natural constituents in
the raw water.
The flow to the R/O units is regulated with a flow control valve based on the amount of product water to
be produced by the unit. Feed pressures to the units are expected to rise as the membranes age. Initial
feed pressures were 100 psi with a five year projected pressure of 120 psi. This pressure is also affected
by the degree of salinity of the feedwater. As the raw water quality decreases, or a brackish water supply
is further developed, more pressure will be needed to produce the same quantity of water.
The R/O membrane is a basic separation process. When the feedwater enters the membrane it is
separated in "Product" and "Concentrate" water. The concentrate is 17% of the feed flow into the unit
and is highly concentrated with the ions from the feedwater. The concentrate is then disposed of through
a separate pipeline to the City's wastewater treatment plant where it is treated and becomes part of the
effluent utilized by the Reclaimed Water System. The R/O membranes pass 83% of the feedwater
through the membrane as it removes calcium and magnesium ions in the water. This water is called the
"Product" water. It is then piped to the next step of treatment.
CO3 « HCO3 « H2CO3 « CO
2 + H20
A grant from the Department of Health and Rehabilitative Services was obtained by the City to pay for a
fluoride chemical feed system. Hydrofluosilicic acid is added to the water as a means to reduce dental
caries. The dosage rate is 0.8 parts per million as fluoride.
With the possibility of more stringent regulations on total trihalomethanes being imposed by EPA,
ammonia facilities were incorporated into the design of the plant. This provision for disinfection with
chloramines is an alternative to major treatment changes should the TTHM regulations become more
stringent.
OTHER LINKS AND REFERENCES
TABLE OF CONTENTS
City of Dunedin Water Division
TEL: 727-738-1840
FAX: 727-736-6205
EMAIL: GKNIPPEL@compuserv.com
PLANT WEB PAGE: http://www.ci.dunedin.dunedin.fl.us:/dunedin/water.htm
1145 Industrial Ave. #1
Escondido CA 92029
TEL: 760-741-7404 and 800-914-9072
FAX: 760-741-5645
EMAIL: support@pwtinc.com; sales@pwtinc.com
WEB PAGE: http://www.pwtinc.com
Contact Persons: Stephen R. Dunham; David L. Kronmiller Ph.D. ; Horace Wood
Dyer, Riddle, Mills & Precourt, Inc
Civil Engineers - Surveyors - Planners
1505 East Colonial Drive
PO Box 53805
Orlando FL 32853-8505
TEL: 407-896-0594
FAX: 407-896-4836
EMAIL: drmp@drmp.com
WEB PAGE: http://www.worldramp.net/~drmp
401 Jones Road
Oceanside, CA 922054
TEL: 760-901-2500
FAX: 760-901-2578
1-800-CPA-PURE
Contact Person: Dr. Mark Wilf, PhD
Technical Market Support Director
EMAIL: mwilf@hydranautics.com
WEB PAGE: http://www.hydranautics.com
Larry Pelegrin, Business Development Manager
email: lpelegrin@de.hydranautics.com
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SUMMARY DATA
Startup Year 1991 Process NF/RO Capacity (MGD) 9.5; expandable to 12MGD Recovery Rate (%) 83 Pretreatment potassium permanganate, greensand pressure filters, sulfuric acid, antiscalant (polyacrylic acid), 5 micron polyprophylene cartridge filters Post-Treatment degasification, chlorination, fluoridation, pH adjustment, sodium hydroxide Feed Water Composition 350/1600 mg/L Product Water Composition TDS = 268 mg/L; ph = 8.05 Concentrate Disposal discharge to wastewater treatment plant to reclaim for irrigation
COSTS*
CAPITAL COST ($000) O & M COSTS ($000) Building Electric Power 420 Plant Equipment Steam
Wells or feed intake O&M Personnel 392 Product tanks
Parts, Chemicals 414 Brine Disposal
Replacement Membranes 175 Other costs
Annual Debt Service 583 TOTAL 11,132 TOTAL 1984
*Source: Leitner & Associates, Survey of U. S. Costs and
Water Rates for Desalination and Membrane Softening Plants, Water
Treatment Technology Program Report No. 24, July 1997: U. S. Bureau of
Reclamation Water
Treatment Engineering & Research Group

OTHER PLANT CHARACTERISTICS*

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FLORIDA WATER RESOURCES JOURNAL