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CITY OF DUNEDIN
REVERSE OSMOSIS WATER TREATMENT FACILITY



PLANT NAME
City of Dunedin Reverse Osmosis Water Treatment Facility
Address
Box 1401 Country Road 1
Dunedin, Florida 34698


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CONTACT PERSON
Gerald Knippel, Division Director
City of Dunedin Water Division
TEL: 727-738-1840
FAX: 727-736-6205
EMAIL: GKNIPPEL@compuserv.com
PLANT WEB PAGE: http://www.ci.dunedin.dunedin.fl.us:/dunedin/water.htm

PLANT SUPPLIER
Professional Water Technologies
1145 Industrial Ave. #1
Escondido CA 92029
TEL: 760-741-7404 and 800-914-9072
FAX: 760-741-5645
EMAIL: support@pwtinc.com; sales@pwtinc.com
WEB PAGE: http://www.pwtinc.com
Contact Persons: Stephen R. Dunham; David L. Kronmiller Ph.D. ; Horace Wood

PLANT CONSULTANT
DRMP
Dyer, Riddle, Mills & Precourt, Inc
Civil Engineers - Surveyors - Planners
1505 East Colonial Drive
PO Box 53805
Orlando FL 32853-8505
TEL: 407-896-0594
FAX: 407-896-4836
EMAIL: drmp@drmp.com
WEB PAGE: http://www.worldramp.net/~drmp

MEMBRANE SUPPLIER
Hydranautics
401 Jones Road
Oceanside, CA 922054
TEL: 760-901-2500
FAX: 760-901-2578
1-800-CPA-PURE
Contact Person: Dr. Mark Wilf, PhD
Technical Market Support Director
EMAIL: mwilf@hydranautics.com
WEB PAGE: http://www.hydranautics.com Larry Pelegrin, Business Development Manager
email: lpelegrin@de.hydranautics.com


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SUMMARY DATA

Startup Year1991
ProcessNF/RO
Capacity (MGD)9.5; expandable to 12MGD
Recovery Rate (%)83
Pretreatmentpotassium permanganate, greensand pressure filters, sulfuric acid, antiscalant (polyacrylic acid), 5 micron polyprophylene cartridge filters
Post-Treatmentdegasification, chlorination, fluoridation, pH adjustment, sodium hydroxide
Feed Water Composition350/1600 mg/L
Product Water CompositionTDS = 268 mg/L; ph = 8.05
Concentrate Disposaldischarge to wastewater treatment plant to reclaim for irrigation


COSTS*

CAPITAL COST ($000)O & M COSTS ($000)
  
Building Electric Power 420
Plant Equipment Steam 
Wells or feed intake O&M Personnel 392
Product tanks  Parts, Chemicals 414
Brine Disposal  Replacement Membranes 175
Other costs  Annual Debt Service 583
TOTAL11,132TOTAL1984


*Source: Leitner & Associates, Survey of U. S. Costs and Water Rates for Desalination and Membrane Softening Plants, Water Treatment Technology Program Report No. 24, July 1997: U. S. Bureau of Reclamation Water Treatment Engineering & Research Group

OTHER PLANT CHARACTERISTICS*

*via http://www.ci.dunedin.fl.us:/dunedin/water.htm








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PRE-TREATMENT
POTASSIUM PERMANGANATE INJECTION AND PRESSURE FILTRATION

Water entering the plant is called raw water. Upon entry, potassium permanganate is injected to convert soluble ferrous iron to insoluble ferric iron so it can be filtered out. Another benefit to potassium permanganate injection is the oxidation of hydrogen sulfide (which gives the rotten egg odor). This oxidation process is vital to the plant operation in that it filters out iron and sulfur bacteria which would otherwise deposit on the membrane surface and cause fouling. It also enables the City to "BLEND" filtered water back with the reverse osmosis (R/O) product water to naturally stabilize the water. This process will be discussed further during the stabilization process.

The water then enters the greensand pressure filters utilizing the water pressure provided by the supply wells. The filters are constructed as horizontal cylinders with layers of filtering material. The top layer is anthracite. It filters out the precipitated insoluble iron produced by the injection of the potassium permanganate. Manganese greensand is the middle layer. This layer absorbs any residual potassium permanganate left over in the water. It also filters out and converts any iron still left in the water at this point. The final layers are multi-sized gravel to support the upper layers and provides filtering for any particles which may have passed through the upper layers. All of the water entering the plant passes through this iron removal process.

SULFURIC ACID AND ANTISCALANT INJECTION

Sulfuric acid is added to lower the pH of the water to prevent calcium carbonate scaling on the R/O membranes. Antiscalant (polyacrylic acid) is added to prevent calcium sulfate and barium sulfate scaling on the membrane. Any scaling on the membrane surface would prevent the passage of the water through the membrane. As scaling occurs, the pressure it takes to force the water through the membrane increases, which in turn increases the power requirement.

MICRON FILTRATION

After the injection of chemicals to prevent scaling on the membranes, the water passes through a series of 5 micron polypropylene cartridge filters. These remove any silt, turbidity, or debris larger than 5 micron which could cause irreparable damage to the membrane surface. Bacteria or other organic matter can also be filtered out during this process. The micron filters cannot be cleaned and/or reused. They are changed out as the pressure loss across them dictates or the water quality from them deteriorates to a point that possible damage to the R/O membranes could occur. This step is the last and most important in the pre-treatment process the membranes. The water is then termed pre-treated feedwater. All treatment done to this point is to protect the RO membranes from any scaling or fouling from natural constituents in the raw water.


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REVERSE OSMOSIS SCHEMATIC

Membrane Softening RO Units
The feed water pressure at this point is about 20 to 30 pounds per square inch. The R/O process requires pressure to force the water through a semi-permeable membrane, i.e. overcome the osmotic pressure. To provide this added pressure requirement, high pressure pumps are located between the micron filters and the R/O units. The pumps are a "manifolded" design. This means that all five of the pumps are available to pressurize the manifold pipe which supplies the feedwater to the R/O units.

The flow to the R/O units is regulated with a flow control valve based on the amount of product water to be produced by the unit. Feed pressures to the units are expected to rise as the membranes age. Initial feed pressures were 100 psi with a five year projected pressure of 120 psi. This pressure is also affected by the degree of salinity of the feedwater. As the raw water quality decreases, or a brackish water supply is further developed, more pressure will be needed to produce the same quantity of water.

The R/O membrane is a basic separation process. When the feedwater enters the membrane it is separated in "Product" and "Concentrate" water. The concentrate is 17% of the feed flow into the unit and is highly concentrated with the ions from the feedwater. The concentrate is then disposed of through a separate pipeline to the City's wastewater treatment plant where it is treated and becomes part of the effluent utilized by the Reclaimed Water System. The R/O membranes pass 83% of the feedwater through the membrane as it removes calcium and magnesium ions in the water. This water is called the "Product" water. It is then piped to the next step of treatment.


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POST-TREATMENT

Degasification and Stabilization
The product water from the RO membranes at this point is very unstable and aggressive. There is very little calcium, magnesium, or alkalinity in the water. In order to provide a stabile, cost effective product to the consumer, filtered raw water is "Blended" with the R/O product water. This provides some natural stability to the water while reducing the cost of production. The blend water is filtered through the greensand pressure filters and 20 micron cartridge filters to ensure quality. The degasification process removes any residual hydrogen sulfide in addition to stripping carbon dioxide.Carbon dioxide is indicative of corrosive water and results when pH of the feedwater is lowered and carbonate changes to bicarbonate and ultimately to carbon dioxide and water:

CO3 « HCO3 « H2CO3 « CO 2 + H20

Degasification is performed by mixing air with the water to remove the hydrogen sulfide and carbon dioxide as gasses. The water enters two cylindrical towers from the top of the units and cascades downwards across a packing material. To more effectively remove the gasses, air is induced in the bottom of the units. The gasses emitted from these units is vented to the atmosphere. After the water exits the degasifier towers, it enters the clearwell located underneath.

Chlorination, pH Adjustment, Fluoridation, Ammonia Injection
As the water enters the clearwell, chlorine is added for disinfection. The clearwell was designed to allow for maximum contact between the chlorine and the water for complete disinfection. A small amount of sodium hydroxide is added to the water to increase the pH of the water. This provides for a more stable water that is non-corrosive nor scale forming in the distribution system.

A grant from the Department of Health and Rehabilitative Services was obtained by the City to pay for a fluoride chemical feed system. Hydrofluosilicic acid is added to the water as a means to reduce dental caries. The dosage rate is 0.8 parts per million as fluoride. With the possibility of more stringent regulations on total trihalomethanes being imposed by EPA, ammonia facilities were incorporated into the design of the plant. This provision for disinfection with chloramines is an alternative to major treatment changes should the TTHM regulations become more stringent.

Ground Storage, High Service Pumps
The water is pumped from the clearwell to the 2-two million gallon ground storage tanks located on plant site. At this point the water is available for pumping to the consumer.


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OTHER LINKS AND REFERENCES

CITY OF DUNEDIN, FLORIDA

FLORIDA WATER RESOURCES JOURNAL

Janice K. Magdziasz and Steven J. Duranceau, "Effects of Water Treatment Plant Residuals on Advance Wastewater Options: Dunedin's Experience," Florida Water Resources Journal, June 1995
SOUTHEAST DESALTING ASSOCIATION

"Facility Profile: Dunedin Reverse Osmosis Water Treatment Facility," SEDA Newsletter, February 1998; PO Box 8900, Jupiter FL 33468-8900
PROFESSIONAL WATER TECHNOLOGIES

HYDRANAUTICS


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ARTICLES ON DESALTING PLANTS IN FLORIDA FROM THE
FLORIDA WATER RESOURCES JOURNAL

DESALINATION IN FLORIDA & WORLDWIDE*
*via http://www2.hawaii.edu/~nabil/desaltbk.htm

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